Greg:
There is an implicit relationship among the 3 correlations. That is, if X1 and X2 are strongly positively correlated, and X1 and X3 are strongly positively correlated, then X2 and X3 can't be strongly negatively correlated. The MCMC algorithm doesn't know this relationship, so new proposals will sometimes be inadmissable. The proposal will then be rejected. The result is that the MCMC algorithm isn't as efficient as it could be if the relationship was enforced, but you should still get a valid sample from the posterior.
Gary